This study employed DIESEL-RK simulation software to investigate the effects of three combustion chamber geometries (Baseline Bowl, Re-entrant Bowl, and Omega Bowl) on the combustion and emission characteristics of an AVL 5402 diesel engine. The results showed that the Omega Bowl provided the best overall performance, increasing engine power by 6.7%, reducing brake specific fuel consumption (BSFC) by 2.6%, and lowering NOₓ emissions by 11.8% compared with the baseline configuration. However, PM emissions increased by 12.1% due to stronger spray interaction. To address this limitation, the operating parameters of the Omega Bowl were optimized. The optimal condition, consisting of SOI = 10° BTDC, SR = 1.2, and Pin = 1,25 bar, reduced NOₓ and PM emissions by 28.7% and 12.6%, respectively, while slightly improving engine power and fuel economy. The results demonstrate that the combined optimization of combustion chamber geometry and operating parameters is an effective approach for improving diesel engine performance and reducing emissions.